How To Make Index Use In Query Execution

I have the below query for which ename column has an index. As of my knowledge below queries 1st and 2st will not use index. Hence i used the 3rd statement and that too its not using the index. Finally i used the 4th query, but even the 4th query is not using the index. Then how do i make this query to use my index??? Do i need to create a function based index for this?

1. select * from emp where ename !='BH' ;
2. select * from emp where ename <> 'BH';
3. select * from emp where ename not in ('BH');
4. select * from emp where ename < 'BH' or ename > 'BH';